Lithium alloy research does not directly lead to the generation of lithium ion batteries, rather than lithium alloy in lithium ion battery appear before has been studied the that makes the lithium ion battery are carbon materials in the application of lithium ion battery.

Carbon materials used for lithium ion battery research is from the 1980 s, but for carbon materials in the lithium behavior before that started the research. In the early 1950 s, Herold Li-graphite embedded synthesized compounds (GIC). In 1976, Besenhard lithium can be found from the solution electrochemical embedded into graphite. But, in the process of charging and discharging due to the expansion of the graphite structure and the macroscopic structure of the collapse, the problem can't be solved. In the early 1980 s been reported in molten lithium lithium in with the combination of carbon into research, found LiC6 can be used as a battery anode, this need to solve the lithium ion battery cathode carbon as a prelude to study. In 1985, the Japanese company to put forward the disorder with Sony not graphitization carbon as battery anode, which invented the lithium ion battery. Later, Sony company successfully launched to LiCOO2 for positive, and gather furfuryl alcohol resin (PFA) pyrolysis carbon (Canon NB-7L Battery) for the negative lithium ion battery, so that the lithium ion battery have already commercial.

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