Managed to creep back to the house, put 3 litres of water into the radiator (I'm assuming that's not normal!) then turned the engine over again. Temp shot up really fast so turned it off again. Added another litre or so of water, but this time when i opened the cap there was a 'burp' from the left side of the engine (looking from the front) like there was an air block of some sort. Engine temp stayed OK for the 5 mins i ran it so went for a wee drive. Hot air again, engine running OK but I'll check under the car tomorrow morning I guess.
Now, what could have caused this? There was a large puddle under the car from stopping at the house earlier on tonight but it didn't leak once I put the water in. The cambelt was done last month and it had a new radiator about 3 months ago. Any ideas?